鹼式乙酸鉻 是一種配位化合物 ,化學式為[Cr3 O(OAc)6 (H2 O)3 ]OAc (OAc為CH3 CO2 − )。它可由氯化鉻 六水合物和氫氧化鈉 於水中反應,其沉澱再和無水乙酸 反應製得;若和氘代乙酸反應,則得到[Cr3 O(O2 CD3 )6 (H2 O)3 ](O2 CCD3 )。[1] 它在DMF 中和苯甲酸 煮沸後,再和高氯酸 反應,可以得到[Cr3 O(OPh)6 (H2 O)3 ]ClO4 ·solv 。[2] 它和硅鉬酸鉀 在pH 2下反應,可以得到KH2 [Cr3 O(O2 CCH3 )6 (H2 O)3 ][SiMo12 O40 ]·11H2 O,鎢類似物 可通過相似方法反應得到。[3]
參考文獻 [ 編輯 ]
^ David M. Low, Gopalan Rajaraman, Madeleine Helliwell, Grigore Timco, Joris van Slageren, Roberta Sessoli, Stefan T. Ochsenbein, Roland Bircher, Christopher Dobe, Oliver Waldmann, Hans-Ulrich Güdel, Mark A. Adams, Eliseo Ruiz, Santiago Alvarez, Eric J. L. McInnes. A Family of Ferro- and Antiferromagnetically Coupled Decametallic Chromium(III) Wheels . Chemistry - A European Journal. 2006-02-01, 12 (5): 1385–1396 [2023-03-21 ] . ISSN 0947-6539 . doi:10.1002/chem.200501041 (英語) .
^ Batsanov, A. S.; Struchkov, Yu. T.; Gerbeleu, N. V.; Timko, G. A.; Manole, O. S. Synthesis and crystal structure of (μ3-oxo)hexa(benzoato)triaquatrichromium(III) perchlorate. Koordinatsionnaya Khimiya , 1994. 20 (11): 833-837.
^ Xiaoshu Qu, Lin Xu, Yunfeng Qiu, Guanggang Gao, Fengyan Li, Yanyan Yang. New Series of Porous Ionic Crystals Constructed from Various Polyoxometalate Anions and Macrocations: Syntheses, Crystal Structures, and Comparison with Diverse Spatial Arrangement . Zeitschrift für anorganische und allgemeine Chemie. 2007-06, 633 (7): 1040–1047 [2023-03-21 ] . doi:10.1002/zaac.200600330 . (原始內容存檔 於2023-03-21) (德語) .