N-亚磺酰基苯胺
| N-亞磺酰基苯胺 | |
|---|---|
| |
| IUPAC名 (Phenylimino)-λ4-sulfanone[1] | |
| 別名 | N-thionylaniline, phenyliminooxosulfurane, N-sulfinylbenzenamine |
| 識別 | |
| CAS號 | 1122-83-4 
|
| PubChem | 70739 |
| ChemSpider | 63904 |
| SMILES |
|
| 性質 | |
| 化學式 | C6H5NSO |
| 摩爾質量 | 139.18 g·mol⁻¹ |
| 外觀 | yellowish oil |
| 密度 | 1.236 g/mL |
| 沸點 | 88–95 °C (17–20 mm.) |
| 危險性 | |
GHS危險性符號 
| |
| GHS提示詞 | Danger |
| H-術語 | H315, H319, H334, H335 |
| P-術語 | P261, P264, P271, P280, P285, P302+352, P304+340, P304+341, P305+351+338, P312, P321, P332+313, P337+313, P342+311 |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
N-亞磺酰基苯胺是有機硫化合物，化學式C6H5NSO，這亞磺酰胺是稻草色液體；親雙烯體；[2]在金屬有機化合物中可作為配體。[3]
製備及結構[編輯]
- 3 PhNH2 + SOCl2 → PhNSO + 2 [PhNH3]Cl
單晶繞射表明結構和二氧化硫或二亞氨基硫有相似之處，碳－氮＝硫＝氧二面角為–1.60°。[5]
參考文獻[編輯]
- ^ International Union of Pure and Applied Chemistry. Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013. The Royal Society of Chemistry. 2014: 1032. ISBN 978-0-85404-182-4. doi:10.1039/9781849733069.
- ^ Kresze, G.; Wucherpfennig, W. New Methods of Preparative Organic Chemistry V: Organic Syntheses with Imides of Sulfur Dioxide. Angewandte Chemie International Edition in English. 1967, 6 (2): 149–167. PMID 4962859. doi:10.1002/anie.196701491.
- ^ Hill, A. F., "Organotransition metallic chemistry of sulfur dioxide analogs", Adv. Organomet. Chem. 1994, 36, 159-227
- ^ Rajagopalan, S.; Advani, B. G.; Talaty, C. N. Diphenylcarbodiimide. Organic Syntheses. 1969, 49: 70. doi:10.15227/orgsyn.049.0070..
- ^ Romano, R.M; Della Védova, C.O; Boese, R. A Solid State Study of the Configuration and Conformation of O=S=N–R (R=C6H5 and C6H3(CH3–CH2)2-2,6). Journal of Molecular Structure. 1999, 475 (1): 1–4. Bibcode:1999JMoSt.475....1R. doi:10.1016/S0022-2860(98)00439-6.