乙酸鑥

乙酸鑥是鑥的乙酸鹽，化學式為Lu(CH₃COO)₃。

製備[編輯]

乙酸鑥可由氧化鑥和氣態乙酸^[1]或50%乙酸溶液^[2]反應得到。

乙酸鑥和氟化銨反應，生成氟化鑥：

Lu(CH₃COO)₃ + 3 NH₄F → LuF₃ + 3 CH₃COONH₄

氟硼酸鹽（如[BMIM]BF₄^[3]）水解生成的F−
也能與Lu3+
產生沉澱。^[4]

和磷酸反應，生成磷酸鑥：^[5]

Lu(CH₃COO)₃ + H₃PO₄ → LuPO₄ + 3 CH₃COOH

^ Janina Wysocka-Lisek. Study of topochemical preparation of rare earth acetates（波蘭文）. Biuletyn Lubelskiego Towarzystwa Naukowego, Matematyka-Fizyka-Chemia, 1981. 23 (2): 145-149.
^ Xina Graehlert, Graehlert Starke. Preparation, thermogravimetry, and IR spectra of rare earth acetates. Wissenschaftliche Zeitschrift der Technischen Universitaet Chemnitz, 1992. 34 (2): 219-229.
^ 註釋：原文為BMIM = 1-butyl-2-methylimidazolium，疑似寫錯，正確的是1-butyl-3-methylimidazolium
^ Becerro, Ana I.; Gonzalez-Mancebo, Daniel; Ocana, Manuel. Uniform, luminescent Eu:LuF₃ nanoparticles. Journal of Nanoparticle Research, 2015. 17 (1): 1-10. DOI:10.1007/s11051-015-2874-z.
^ Becerro, Ana I.; Ocana, Manuel. Quick synthesis, functionalization and properties of uniform, luminescent LuPO4-based nanoparticles. RSC Advances, 2015. 5 (44): 34517-34524. DOI:10.1039/C5RA05305F.