四羰基(三苯基膦)合鐵

四羰基(三苯基膦)合鐵
識別
CAS號	14649-69-5
性質
化學式	C22H15FeO4P
摩爾質量	430.17 g·mol−1
外觀	黃色晶體
密度	1.41 g·cm−3（19 °C）
熔點	200—204 °C（473—477 K）（分解）
沸點	185 °C（真空，升華）
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

四羰基(三苯基膦)合鐵是一種有機鐵化合物，化學式為[(C₆H₅)₃P]Fe(CO)₄。它可由五羰基鐵和三苯基膦在汞燈照射下於環己烷中（或鈀催化下於甲苯中^[4]）反應得到^[5]；它也可以在三羰基(1,3-丁二烯)合鐵和三苯基膦在40 °C的反應中生成。^[6]它和SnX₄反應，可以得到Fe(CO)₃X[P(C₆H₅)₃]SnX₃（X=Cl, Br）。^[7]

參考文獻[編輯]

^ ^1.0 ^1.1 K. Farmery, M. Kilner. Substitution reactions of dihydridotetracarbonyliron. Journal of the Chemical Society A: Inorganic, Physical, Theoretical. 1970: 634 [2023-03-10]. ISSN 0022-4944. doi:10.1039/j19700000634 （英語）.
^ Paul E. Riley, Raymond E. Davis. Crystal structures at -35.degree.C of tetraphenylphosphonium (triphenylphosphine)tetracarbonylmanganate and (triphenylphosphine)tetracarbonyliron. Inorganic Chemistry. 1980-01, 19 (1): 159–165 [2023-03-10]. ISSN 0020-1669. doi:10.1021/ic50203a033. （原始內容存檔於2023-03-10）（英語）.
^ R.J. Angelici, E.E. Siefert. Substitution reactions of trigonal bipyramidal complexes of iron pentacarbonyl. Journal of Organometallic Chemistry. 1967-05, 8 (2): 374–376 [2023-03-10]. doi:10.1016/S0022-328X(00)91055-6. （原始內容存檔於2018-06-30）（英語）.
^ Michel O. Albers, Neil J. Coville, Eric Singleton. The use of supported transition metals and metal oxides as catalysts for the metal carbonyl substitution reaction. Journal of the Chemical Society, Chemical Communications. 1982, (2): 96 [2023-03-10]. ISSN 0022-4936. doi:10.1039/c39820000096 （英語）.
^ Lewis, J.; Nyholm, R. S.; Sandhu, S. S.; Stiddard, M. H. B.. Photochemically-induced substitution reactions of pentacarbonyliron. Journal of the Chemical Society Aug. 1964: 2825-2827. ISSN 0368-1769
^ Murdoch, H. D.; Weiss, E. Butadieneiron carbonyl compounds. Helvetica Chimica Acta, 1962. 45: 1156-1161.
^ Tetsuo Takano. The Reactions of Stannic Halides with Some Triphenylphosphine, -arsine and -stibine-substituted Iron Carbonyls. Bulletin of the Chemical Society of Japan. 1973-02, 46 (2): 522–523 [2023-03-10]. ISSN 0009-2673. doi:10.1246/bcsj.46.522. （原始內容存檔於2023-03-10）（英語）.

參見[編輯]

三羰基二(三苯基膦)合鐵

[Farmery-1] 1.0 ^1.1 K. Farmery, M. Kilner. Substitution reactions of dihydridotetracarbonyliron. Journal of the Chemical Society A: Inorganic, Physical, Theoretical. 1970: 634 [2023-03-10]. ISSN 0022-4944. doi:10.1039/j19700000634 （英語）.

[2] Paul E. Riley, Raymond E. Davis. Crystal structures at -35.degree.C of tetraphenylphosphonium (triphenylphosphine)tetracarbonylmanganate and (triphenylphosphine)tetracarbonyliron. Inorganic Chemistry. 1980-01, 19 (1): 159–165 [2023-03-10]. ISSN 0020-1669. doi:10.1021/ic50203a033. （原始內容存檔於2023-03-10）（英語）.

[3] R.J. Angelici, E.E. Siefert. Substitution reactions of trigonal bipyramidal complexes of iron pentacarbonyl. Journal of Organometallic Chemistry. 1967-05, 8 (2): 374–376 [2023-03-10]. doi:10.1016/S0022-328X(00)91055-6. （原始內容存檔於2018-06-30）（英語）.

[4] Michel O. Albers, Neil J. Coville, Eric Singleton. The use of supported transition metals and metal oxides as catalysts for the metal carbonyl substitution reaction. Journal of the Chemical Society, Chemical Communications. 1982, (2): 96 [2023-03-10]. ISSN 0022-4936. doi:10.1039/c39820000096 （英語）.

[5] Lewis, J.; Nyholm, R. S.; Sandhu, S. S.; Stiddard, M. H. B.. Photochemically-induced substitution reactions of pentacarbonyliron. Journal of the Chemical Society Aug. 1964: 2825-2827. ISSN 0368-1769

[6] Murdoch, H. D.; Weiss, E. Butadieneiron carbonyl compounds. Helvetica Chimica Acta, 1962. 45: 1156-1161.

[7] Tetsuo Takano. The Reactions of Stannic Halides with Some Triphenylphosphine, -arsine and -stibine-substituted Iron Carbonyls. Bulletin of the Chemical Society of Japan. 1973-02, 46 (2): 522–523 [2023-03-10]. ISSN 0009-2673. doi:10.1246/bcsj.46.522. （原始內容存檔於2023-03-10）（英語）.

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